Synthesis and characterization of new chiral palladium β-diimine complexes

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• 作者：Doris Domin ; David Benito-Garagorri ; Kurt Mereiter ; Christian Hametner ; Johannes Frö ; hlich ; Karl Kirchner
• 关键词：β ; -Diimines ; Chiral ligands ; Palladium(II) ; Square-planar complexes
• 刊名：Journal of Organometallic Chemistry
• 出版年：2007
• 出版时间：1 February 2007
• 年：2007
• 卷：692
• 期：5
• 页码：1048-1057
• 全文大小：339 K

文摘

The synthesis and characterization of a range of chiral β-diimine ligands and their complexes with palladium(II) has been investigated. The introduction of chirality can be easily achieved through a combination of both achiral and chiral building blocks. The absolute configuration of the stereochemical centers has been determined. In addition, representative X-ray structures of both ligands and complexes have been determined.