Perovskite solar cells with different cathode of Al, Ag and AgAl were fabricated.
Cells with AgAl alloy retained 90% of the initial PCE values after aging 48 h.
Cells with AgAl kept the initial Voc during aging 360 h, showing amazing stability.
The superior stability of cells with AgAl is attributed to the formation of AlOX.
AlOX formed boosts electron extraction and inhibits moisture encroachment.