Electrocatalytic reduction of CO₂ to CO in the presence of a mononuclear polypyridyl ruthenium(II) complex

详细信息    查看全文

• 作者：Marzieh Daryanavard^a ; ^b ; Hassan Hadadzadeh^a ; ^{hadad@cc.iut.ac.ir} ; ^{hadadzadeh1347@yahoo.com} ; Matthias Weil^c ; Hossein Farrokhpour^a
• 关键词：Carbon dioxide ; Ruthenium ; Electrocatalyst ; CO2 reduction ; Computational studies
• 刊名：Journal of CO2 Utilization
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：17
• 期：Complete
• 页码：80-89
• 全文大小：1746 K
• 卷排序：17

文摘

Preparation and characterization of a mononuclear Ru(II) complex. Electrocatalytic activity of the Ru(II) complex for the reduction of CO2 to CO in CH3CN. A proposed reaction mechanism for the electrocatalytic reduction of CO2. The DFT calculations indicate that the reaction proceeds in six steps. The optimized structures for the species involved in the electrocatalytic cycle.