文摘
Sr and Nb co-doped Pb(Zr,Ti)O3 ferroelectric ceramics were synthesized by a solid-state reaction method. Rare phenomenon of coexistence of negative and positive electrocaloric effect was found in Sr and Nb co-doped Pb(Zr,Ti)O3 ferroelectric ceramics. High electrocaloric coefficient of −0.25 K mm kV−1 and 0.43 K mm kV−1 were obtained. Reason for the coexistence of negative and positive electrocaloric effect was discussed.