μ-Borole triple-decker complexes as catalysts for oxidative coupling of benzoic acid with alkynes. Structure of a hybrid rhodacyclopentadienyl/borole triple-decker complex

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• 作者：Dmitry A. Loginov ; ^{dloginov@ineos.ac.ru} ; Dmitry V. Muratov ; Yulia V. Nelyubina ; Julia Laskova ; Alexander R. Kudinov ; ^{arkudinov@ineos.ac.ru}
• 关键词：C&minus ; H activation ; Rhodium ; Metal complex catalysis ; Triple-decker complexes
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：393-397
• 全文大小：914 K
• 卷排序：426

文摘

Triple-decker complex with a bridging rhodacyclopentadienyl ligand was described. Triple-decker complexes effectively catalyze coupling of benzoic acid with alkynes. Catalytic selectivity is determined by terminal ligands in triple-decker structure.