Zirconium organophosphonates as high capacity, selective lanthanide sorbents
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- 作者：Jessica Veliscek-Carolana ; Tracey L. Hanleya ; Vittorio Lucab ; vluca@cnea.gov.au" class="auth_mail
- 关键词：Hybrid porous materials ; Lanthanides ; Sorption ; Separations ; Zirconium phosphonate
- 刊名：Separation and Purification Technology
- 出版年：29 May 2014
- 年：2014
- 卷：129
- 期：Complete
- 页码：150-158
- 全文大小：1302 K
文摘
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Novel zirconium organophosphonate coordination networks have been synthesised.
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Selective lanthanide sorption from competitive, acidic solutions observed.
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Fast kinetics and high capacity provide commercial viability.
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Materials are hydrolytically and radiolytically stable.
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Porosity and sorption capacity controllable by composition.