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Efficient visible light photocatalytic NOx removal with cationic Ag clusters-grafted (BiO)2CO3 hierarchical superstructures
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Microstructural optimization and surface cluster-grafting were firstly combined.

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Cationic Ag clusters were grafted on the surface of (BiO)2CO3 superstructures.

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The Ag clusters-grafted BHS displayed enhanced visible light photocatalysis.

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Direct interfacial charge transfer (IFCT) from BHS to Ag clusters was proposed.

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The charge transfer process and the dominant reactive species were revealed.

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