Preparation of UV-curing polymer-ZrO2 hybrid nanocomposites via auto-hydrolysis sol-gel process using zirconium oxychloride octahydrate coordinated with organic amine
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- 作者：Yanyan Cui ; Zhikang Chen ; Xiaoxuan Liu ; p-xxliu@gdut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; p_xxliu@aliyun.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Sol-gel process ; Hybrid coatings ; UV-curing
- 刊名：Progress in Organic Coatings
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：100
- 期：Complete
- 页码：178-187
- 全文大小：2458 K
文摘
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Nanozirconia is firstly obtained from zirconium oxychloride octahydrate via auto-hydrolysis sol-gel process without adding H2O.
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Triethylamine and dimethylaminoethyl methacrylate are used as acid-binding agent to control the shape and size of particles.
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UV-curing organic/inorganic hybrid system is prepared based on epoxy acrylate and zirconia nanoparticles.
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An organic/inorganic interpenetrating network is likely formed with the proper ratio of zirconia sol.