POSS-containing fluorosilicone multi-block methacrylate copolymers were synthesized.
Bigger fluorinated side groups were easy to migrate onto the film surface.
Fluorine-rich surface and low water contact angle hysteresis were obtained.
The supercooled water droplet could easily slip away from the tilted copolymer surface.
Ice shear strength could be reduced by the incorporation of POSS block.