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Structural, vibrational and optical properties of a new organic-inorganic material: (C5H8N3)2[BiCl5]
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[C5H8N3]2BiCl5 is a new zero dimensional hybrid compound.

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Anionic and cationic groups are linked thanks to Nsingle bondclass="glyphImg imgLazyJSB">H⋯Cl hydrogen bonds.

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Optical absorption and photoluminescence measurements were studied.

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Raman and Infrared spectra were interpreted and assigned focused on the density functional theory (DFT) method.

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