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TiO2 alterations with natural aging: Unveiling the role of nitric acid on NIR reflectance
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The near infrared (NIR) reflectance of TiO2 containing surfaces was investigated.

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The NIR reflectance of anatase containing materials increased upon natural aging.

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The effect was ascribed to the generation of HNO3 by NOx photocatalytic degradation.

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This combines positive air purification and improvements in optical-radiative properties.

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The finding is a countertrend, as typically aged materials lose solar reflectance.

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