pH-Induced cucurbit[7]uril hydrogels: Understanding microenvironment of the aggregates through excited state reactivity of dibenzyl ketones
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- 作者：Mahesh Pattabiramana ; pattabiramm2@unk.edu" class="auth_mail" title="E-mail the corresponding author ; Murthy V.S.N. Maddipatlab ; V. Ramamurthyb
- 刊名：Journal of Photochemistry & Photobiology, A: Chemistry
- 出版年：2016
- 出版时间：30 June 2016
- 年：2016
- 卷：324
- 期：Complete
- 页码：53-61
- 全文大小：1555 K
文摘
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Unprecedented understanding about molecular mobility and reactivity within CB7 hydrogels based on photochemical and NMR diffusion experiments.
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Qualitative measure of structural rigidity of CB7 aggregates.
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Effect of acidity, temperature, and concentration on hydrogel stability studied.
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Studies suggest high tunability of physical and mechanical properties.
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Indication of possible aggregation of CB7 to form super cages.