Bulky 2,6-diphenylphenylsulfanyl substituents efficiently inhibit aggregation in phthalocyanines and tetrapyrazinoporphyrazines and control their photophysical and electrochemical properties
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- 作者：Petr Zimcika ; zimcik@faf.cuni.cz" class="auth_mail" title="E-mail the corresponding author ; Anna Malkovaa ; Lenka Hrubab ; Miroslav Miletina ; Veronika Novakovab ; veronika.novakova@faf.cuni.cz" class="auth_mail" title="E-mail the corresponding author
- 关键词：Phthalocyanine ; Newman-Kwart rearrangement ; Fluorescence ; Singlet oxygen ; Aggregation ; Electrochemistry
- 刊名：Dyes and Pigments
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：136
- 期：Complete
- 页码：715-723
- 全文大小：921 K
文摘
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2,6-diphenylbenzenethiol was synthesized by Newman-Kwart rearrangement.
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Octasubstituted phthalocyanines and tetrapyrazinoporphyrazines were synthesized.
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The bulky substituents fully inhibited aggregation in toluene.
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2,6-diphenylphenylsulfanyl influenced photophysical and electrochemical properties.