Oxidation of aliphatic and aromatic CH bonds by t-BuOOH catalyzed by μ-nitrido diiron phthalocyanine

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• 作者：Evgeny V. Kudrik^a ; ^b ; Alexander B. Sorokin^a ; ^{alexander.sorokin@ircelyon.univ-lyon1.fr}
• 关键词：Oxidation ; Catalysis ; Alkanes ; Cyclohexane ; Phthalocyanine ; μ-Nitrido dimer ; Hydroperoxides
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：499-505
• 全文大小：892 K
• 卷排序：426

文摘

Formation of the diiron peroxo complex Fe(IV)NFe(III)OOtBu. Homolytic cleavage of OO bond leads to two active species reacting with CH bonds. Oxidation of cyclohexane, cyclohexene, toluene and benzene.