Stability of nickel catalyst supported by mesoporous alumina for hydrogen iodide decomposition and hybrid decomposer development in sulfur-iodine hydrogen production cycle

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• 作者：Jin Young Choi ; Hee Cheon NO ; Young Soo Kim
• 关键词：Hydrogen production ; Thermo-chemical cycle ; SI cycle ; Hydrogen iodide decomposition ; Nickel alumina catalyst
• 刊名：International Journal of Hydrogen Energy
• 出版年：6 March, 2014
• 年：2014
• 卷：39
• 期：8
• 页码：3606-3616
• 全文大小：2344 K

文摘

We propose a hybrid HI decomposer, which combines a high-temperature catalytic decomposition reactor with a dual bed temperature-swing decomposer. For the high temperature step, we screened and identified a catalyst that is stable above 700聽掳C by preparing nickel catalysts supported on mesoporous alumina and evaluating their activity toward the high-temperature catalytic decomposition reaction. The catalysts achieved HI decomposition yields up to 23% at 650聽掳C and maintained over 20% yield after 100聽h聽of operation. For the temperature-swing process, we investigated the adsorption, desorption, and regeneration efficiency, and the optimal regeneration temperature of nickel catalysts supported on silica/alumina adsorbents. The optimal regeneration temperature was 400聽掳C. Based on these results, we propose hybrid HI decomposers in two configurations: 1) residual HI decomposer and 2) HI concentrator. The residual HI decomposer improves the overall conversion efficiency to levels above the thermodynamic limit, while the HI concentrator increases the concentration of HI by simple temperature control, even at below-azeotropic HI concentrations.