Experiments on laboratory and field scale have been performed to study physical and chemical interactions in the short term between CO2 and impurities, brine and reservoir rock.
Focused on the laboratory scale, tests with pure CO2 and CO2 containing SO2 at 150 barg and 45 °C were done. As core findings: the porosity was much lower after the injection of CO2 with 5%v of SO2; the effluent pH for the pure CO2 injection tests was in the range of 7–8 and in the range of 1–2 if impure CO2 was injected; regarding the ion migration, chemical modifications were detected with the mixture of CO2 and CO2, being mainly based on the modification of Mg2+ and SO42−.
The field scale tests were based on the injection of CO2 and synthetic air in Hontomín Technology Development Plant. The fluid density was calculated using the two pressure transmitters installed at the bottom of the injection well; comparing the base case (pure CO2) with the case of CO2 containing 5.1%v of air, the density decreases from 840 kg/m3 to 775 kg/m3 at the storage conditions (i.e. 8% of diminution in the density).
The well head pressure (WHP) needed to inject the mixture of CO2 and 5.1%v of air increased from 80 bar (corresponding to the case of pure CO2, to 90 bar. That effect reveals that the injection of N2 and O2 in concentrations of 5.1%v of air (79% N2 and 21% O2) is less efficient than the injection of pure CO2.