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Dual binding site assisted chromogenic and fluorogenic discrimination of fluoride and cyanide by boryl functionalized BODIPY
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文摘

A new boron-dipyrromethene (BODIPY) derivative bearing a boronate group (1) had been designed and synthesized.

The addition of F and CN to 1 in THF solution induced a rapid color change from rose pink to indigo and faint pink, respectively.

The emission color of the 1 changed from red to indigo and green in presence of F and CN, respectively.

The preferential binding of cyanide occurs at the boron center of BODIPY core. On the other hand, fluoride binding occurs at the boron center of BODIPY core and boronate moiety.

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