Metal-free, C-H arylation of indole and its derivatives with aryl diazonium salts by visible-light photoredox catalysis
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- 作者：Ying-Peng Zhang ; yingpengzhang@126.com" class="auth_mail" title="E-mail the corresponding author ; Xiao-Long Feng ; Yun-Shang Yang ; yangguang@lut.cn" class="auth_mail" title="E-mail the corresponding author ; Bi-Xia Cao
- 关键词：C-arylated indoles ; Metal-free ; Aryl diazonium salts ; Visible light ; Free radical
- 刊名：Tetrahedron Letters
- 出版年：2016
- 出版时间：25 May 2016
- 年：2016
- 卷：57
- 期：21
- 页码：2298-2302
- 全文大小：3812 K
文摘
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C–H arylation of indole with aryl diazonium salts was catalyst by Rhodamine B.
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This method only requires green light and room temperature.
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The mechanism of this reaction relies on free radical reaction.