Control of dimensionality and topology in nickel and cobalt coordination polymers containing adamantane-based dicarboxylate and long-spanning dipyridyl ligands

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• 作者：Jamelah Z. Travis^a ; Cassi J. LaRose^b ; Robert L. LaDuca^b ; ^{laduca@msu.edu}
• 关键词：Nickel ; Cobalt ; Crystal structure ; Coordination polymer ; Antiferromagnetism ; Ferromagnetism
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 February 2017
• 年：2017
• 卷：456
• 期：Complete
• 页码：158-170
• 全文大小：4656 K
• 卷排序：456

文摘

Nickel and cobalt coordination polymers with adamantanedicarboxylate ligands. Long-spanning dipyridyl or dipyridylamide coligands. 2D and 3D topologies including a very rare self-penetrated msw network. Dimeric units exhibit divergent antiferromagnetic or ferromagnetic coupling.