Fourier transform microwave spectroscopy of metal nitrides and imides: Quadrupole structure in ScN (X1危+), YN (X1危+), and BaNH
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- 作者：L.N. Zacka ; b ; M.P. Bucchinoa ; b ; M.K.L. Binnsc ; J.P. Youngc ; P.M. Sheridanc ; sheridap@canisius.edu" class="auth_mail" title="E-mail the corresponding author ; L.M. Ziurysa ; b
- 关键词：Fourier transform microwave/mm-wave spectroscopy ; Hyperfine structure ; Quadrupole coupling constants ; Laser ablation
- 刊名：Journal of Molecular Spectroscopy
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：317
- 期：Complete
- 页码：10-15
- 全文大小：727 K
文摘
- •
Rotational spectrum of ScN and YN (
1危+) measured for the first time.- •
Demonstrated performance of FTmmW spectrometer at 52 GHz.
- •
First determination of nitrogen quadrupole and nuclear spin–rotation constants for ScN, YN, and BaNH.
- •
First determination of scandium quadrupole constant for ScN, suggesting a covalent, diradical structure.
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