Synthesis of terpene derivatives of ethanolamine using telomerization reaction
详细信息 查看全文
- 作者：Wissam Zahreddinea ; b ; Quentin Lelonga ; Iyad Karamé ; b ; Ali Kanjb ; Catherine Pinela ; Laurent Djakovitcha ; Franck Rataboula ; franck.rataboul@ircelyon.univ-lyon1.fr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ethanolamine ; Isoprene ; Telomerization ; Palladium
- 刊名：Tetrahedron Letters
- 出版年：2016
- 出版时间：20 January 2016
- 年：2016
- 卷：57
- 期：3
- 页码：452-457
- 全文大小：1014 K
文摘
- •
New terpenoids have been prepared via telomerization of isoprene and ethanolamine.
- •
The reaction was catalyzed using PPh3/Pd at 90 °C in methanol.
- •
The selectivity of mono and ditelomer families depended on reagent stoichiometry.
- •
The monotelomer family was composed of 6 isomers.