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Disassembly of diruthenium(II,III) tetraacetate with P-N donor ligands
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文摘

Six Ru(II) P–N donor complexes formed by disassembly of [Ru2(μ-O2CMe)4(H2O)2]+.

A mixture of homo- and heteroleptic complexes form dependent on sterics of P–N ligand.

Redox potentials dependent on degree and number of π-acid ligands present.

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