Selective, aerobic oxidation reaction of alcohols by hybrid Pd/ZrO₂/PVA catalytic membranes

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• 作者：Francesca Liguori^a ; Carmen Moreno-Marrodan^a ; Pierluigi Barbaro^a ; ^{pierluigi.barbaro@iccom.cnr.it} ; Haruo Sawa^b
• 关键词：Heterogeneous catalysis ; Palladium ; Nanoparticles ; Alcohols oxidation ; Membranes ; Flow processes
• 刊名：Applied Catalysis A: General
• 出版年：2017
• 出版时间：25 January 2017
• 年：2017
• 卷：530
• 期：Complete
• 页码：217-225
• 全文大小：1150 K
• 卷排序：530

文摘

Pd nanoparticles embedded into hybrid zirconia/polyvinyl alcohol membrane. Partial oxidation reactions of alcohols in the liquid phase under continuous flow. Reaction temperature below 100 °C. No metal leaching, stable, use of hydrophilic solvents, no need of regeneration nor additives.