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The crystal structures of Ni<sub>3+xsub>Sn<sub>4sub>Zn and Ni<sub>6+xsub>Sn<sub>8sub>Zn and their structural relations to Ni<sub>3+xsub>Sn<sub>4sub>, NiSn and Ni<sub>5∿span style='font-style: italic'>δsub>ZnSn<sub>4sub>
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The crystal structures of Ni<sub>6+xsub>Sn<sub>8sub>Zn and Ni<sub>3+xsub>Sn<sub>4sub>Zn were determined using single crystal XRD.

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Topological relations to Ni&ndash;Sn and Ni&ndash;Sn&ndash;Zn compounds were established and discussed.

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Common structural units were identified and their interconnection patterns described.

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