Abatement of the fluorinated antidepressant fluoxetine (Prozac) and its reaction by-products by electrochemical advanced methods

详细信息    查看全文

• 作者：Claudio Salazar^a ; Carlota Ridruejo^b ; Enric Brillas^b ; ^{brillas@ub.edu} ; Jorge Yá ; ñ ; ez^a ; Hé ; ctor D. Mansilla^a ; Ignasi Siré ; s^b ; ^{i.sires@ub.edu} ; ^{isiresa@gmail.com}
• 关键词：Anodic oxidation with electrogenerated H2O2 ; Electro-Fenton ; Fluoxetine ; Oxidation products ; Photoelectro-Fenton
• 刊名：Applied Catalysis B: Environmental
• 出版年：2017
• 出版时间：April 2017
• 年：2017
• 卷：203
• 期：Complete
• 页码：189-198
• 全文大小：1366 K
• 卷排序：203

文摘

Fluoxetine hydrochloride treated with Pt, RuO2-based or BDD anode and H2O2 generation. Faster mineralization by PEF with a BDD anode due to BDD(OH), OH and UVA light. Pseudo-first-order decay by AO-H2O2, EF and, more rapidly, by PEF using a BDD anode. Degradation of fluoxetine with F− and NO3− formation and partial Cl− oxidation to HClO. Detection of 4 primary aromatics, 1 chloroaromatic derivative and 4 carboxylic acids.