Tubular macro-porous titanium membranes

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• 作者：Oana David^a ; Youri Gendel^a ; Matthias Wessling^a ; ^b ; ^{Matthias.Wessling@avt.rwth-aachen.de" class="auth_mail}
• 关键词：Porous titanium hollow fibers ; Dry wet spinning ; Sintering ; Titanium membrane ; Tubular electrode
• 刊名：Journal of Membrane Science
• 出版年：1 July, 2014
• 年：2014
• 卷：461
• 期：Complete
• 页码：139-145
• 全文大小：1874 K

文摘

We present tubular macroporous titanium membranes prepared via a dry-wet spinning process from a polyethersulfone solution loaded with Ti particles (15 渭m) and a subsequent sintering process at various sintering temperatures (1100-1500 掳C) and sintering times (30-75 min). Outer diameter, wall thickness, average pore size and porosity of the Ti tubes were ~4.5 mm, ~350 渭m, 1.6-2.8 渭m and ~30%, respectively. These tubular membranes have excellent mechanical strength, electrical conductivity as well as nitrogen and water permeability. These properties, together with the inherent high corrosion and temperature resistance of titanium make them suitable for a wide range of membrane applications such as microfiltration, porous tubular electrodes for electrochemical membrane reactors; and gas-to-liquid diffuser.