Endothermic features on heating of glasses show that the second glass to liquid transition of water was phenomenologically-mistaken

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• 作者：Maria Cristina Righetti^a ; Elpidio Tombari^a ; G.P. Johari^b ; ^{joharig@mcmaster.ca}
• 关键词：Glass transition ; Water ; Polymer ; Glass phenomenology
• 刊名：Thermochimica Acta
• 出版年：2017
• 出版时间：10 January 2017
• 年：2017
• 卷：647
• 期：Complete
• 页码：101-110
• 全文大小：1107 K
• 卷排序：647

文摘

Glasses formed on cooling a liquid at different rates have different Tl→g s. Glass formed by slow-cooling shows a higher Tg→l than the glass formed by fast-cooling. The second Tg→l of water at 116 K (reported as Tg) is phenomenologically mistaken.