Bioinspired Mn-aminopyridine catalyzed epoxidations of olefins with various oxidants: Enantioselectivity and mechanism
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- 作者：Roman V. Ottenbachera ; b ; ottenbacher@catalysis.ru" class="auth_mail" title="E-mail the corresponding author ; Evgenii P. Talsia ; b ; Konstantin P. Bryliakova ; b
- 关键词：Asymmetric catalysis ; Enantioselective ; Epoxidation ; Hydrogen peroxide ; Manganese ; Mechanism
- 刊名：Catalysis Today
- 出版年：2016
- 出版时间：1 December 2016
- 年：2016
- 卷：278
- 期：part_P1
- 页码：30-39
- 全文大小：1906 K
文摘
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State-of-the-art of asymmetric epoxidations on bioinspired Mn complexes is overviewed.
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Catalysts design and selectivity issues are discussed.
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Available mechanistic data for the Mn catalyzed epoxidations are considered.