Brønsted acidic ionic liquids derived from alkylamines as catalysts and mediums for Fischer esterification: Study of structure–activity relationship

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• 作者：Pralhad A. Ganeshpure ; Gigi George ; Jagannath Das
• 关键词：Ionic liquid ; Esterification ; Acid catalyst ; Acetic acid ; 1-Octanol
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2008
• 出版时间：18 January 2008
• 年：2008
• 卷：279
• 期：2
• 页码：182-186
• 全文大小：110 K

文摘

Esterification of acetic acid with 1-octanol was studied using a series of alkylammonium salts as Brønsted acidic ionic liquids. The following ionic liquids were prepared and used as catalysts and mediums in the esterification reaction; [Et₃NH][HSO₄], [Et₃NH][H₂PO₄], [Et₃NH][BF₄], [Et₃NH][p-CH₃C₆H₄SO₃], [Et₂(PhCH₂)NH][HSO₄], [n-Bu₃NH][HSO₄], [n-Oct₃NH][HSO₄], [Et₂NH₂][HSO₄], [Et₂NH₂][H₂PO₄], [Et₂NH₂][BF₄], [i-Pr₂NH₂][HSO₄], [EtNH₃][HSO₄], [EtNH₃][H₂PO₄], and [EtNH₃][BF₄]. Higher acidity of the anion in the ionic liquid resulted in high yield of the ester. Yield of the ester decreased with increase in the size of the cation. There was no phase separation in the reactions where size of anion and/or cation was bigger.