Dispersed-fluorescence spectroscopy of jet-cooled calcium ethoxide radical (CaOC₂H₅)

详细信息    查看全文

• 作者：Anam C. Paul^a ; Md. Asmaul Reza^a ; Jinjun Liu^a ; ^b ; ^{j.liu@louisville.edu}
• 关键词：Monovalent derivatives of calcium ; Dispersed fluorescence ; CASSCF calculations ; Franck-Condon factors ; Pseudo-Jahn-Teller effect
• 刊名：Journal of Molecular Spectroscopy
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：330
• 期：Complete
• 页码：142-146
• 全文大小：706 K
• 卷排序：330

文摘

Dispersed fluorescence spectra of jet-cooled calcium ethoxide radicals (CaOC2H5). CASSCF calculations of vibrational frequencies and Franck-Condon factors of the Ã12A′/Ã22A″-X̃2A′ transitions. Differences between intensities of the Ã12A′→X̃2A′ and the Ã22A″→X̃2A′ DF spectra due to symmetry. Collision-induced population transfer between two nearly degenerate excited states (Ã1 and Ã2).