Structural diversity and magnetic properties of six metal-organic coordination polymers based on semi-rigid V-shape tetracarboxylic acid ligand
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- 作者：Shanshan Yanga ; 1 ; Yue-Ling Baia ; 1 ; Feifei Xinga ; 1 ; Yongmei Zhaoa ; 1 ; Ming-Xing Lia ; 1 ; Min Shaob ; Shourong Zhua ; 1 ; shourongzhu@shu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Metal-organic frameworks ; V-shape ligand ; Crystal structures ; Syntheses ; Magnetic properties
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：5 April 2016
- 年：2016
- 卷：1109
- 期：Complete
- 页码：161-170
- 全文大小：3256 K
文摘
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Six Mn metal-organic frameworks have been assembled from V-shaped terphenyl tetracarboxylate ligand.
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The coordination number of terphenyl tetracarboxylate ligand varies from 6 to 10, and each ligand links 4–8 Mn(II) ions.
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The first coordination saturated phthalate is presented.
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Compared to H2O solvent, DMF can increase coordination number of the ligand.