Millimeter-wave spectroscopy of syn formyl azide (HC(O)N₃) in seven vibrational states

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• 作者：Nicholas A. Walters ; Brent K. Amberger ; Brian J. Esselman ; R. Claude Woods ; ^{rcwoods@wisc.edu} ; Robert J. McMahon ; ^{mcmahon@chem.wisc.edu}
• 关键词：Formyl azide ; Millimeter-wave ; Rotational spectroscopy ; Vibration-rotation interaction ; Centrifugal distortion
• 刊名：Journal of Molecular Spectroscopy
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：331
• 期：Complete
• 页码：71-81
• 全文大小：1744 K
• 卷排序：331

文摘

Rotational spectra for formyl azide (HC(O)N3) were obtained from 240 to 360 GHz. 1573 rotational transitions were observed for the ground state of syn formyl azide. Six vibrational satellites of syn formyl azide were observed. Excellent agreement: measured, computed vibration-rotation interaction. Thermal decomposition kinetics of formyl azide monitored (half-life t½ = 30 min).