Synthesis and characterization of regioselectively substituted curdlan hetero esters via an unexpected acyl migration
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- 作者：Chih-Ying Chiena ; 5880558873@mail.ecc.u-tokyo.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Yukiko Enomoto-Rogersa ; b ; y-rogers@aist.go.jp" class="auth_mail" title="E-mail the corresponding author ; Akio Takemuraa ; akiot@mail.ecc.u-tokyo.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Tadahisa Iwataa ; atiwata@mail.ecc.u-tokyo.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Curdlan ; Regioselectively ; Hetero ester ; Acyl migration
- 刊名：Carbohydrate Polymers
- 出版年：2017
- 出版时间：2 January 2017
- 年：2017
- 卷：155
- 期：Complete
- 页码：440-447
- 全文大小：1590 K
文摘
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Regioselectively substituted curdlan ester was synthesized.
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An unexpected acyl migration was found in the detritylation.
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Regioselectively substituted ester groups promoted the crystallization.