The synthesis and magnetic properties of monodispersed single-domain nickel nanospheres and highly globular nanostructures of Ni_coreNiO_shell

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• 作者：Xiansong Liu ; Udi Meridor ; Peng Zhao ; Gongbao Song ; Aviad Frydman and Aharon Gedanken
• 关键词：Core-shell structures ; Polyol reaction ; Magnetic properties
• 刊名：Journal of Magnetism and Magnetic Materials
• 出版年：2006
• 出版时间：June 2006
• 年：2006
• 卷：301
• 期：1
• 页码：13-21
• 全文大小：538 K

文摘

Monodispersed single-domain nickel nanospheres have been successfully prepared by the microwave-assisted (MW) polyol method. TEM and AFM analysis reveal that the nickel nanospheres have a size distribution in the 100–180 nm range. Highly globular nanostructures of Ni_coreNiO_shell are achieved by oxidizing the nickel nanospheres in a flow of H₂O₂ and the structure is studied by means of TEM, XPS, and EDAX. The single-domain magnetic structure is confirmed by MFM measurements and the ferromagnetic properties are demonstrated by VSM and SQUID studies. Surprisingly, no shift in the magnetization loop is observed despite the ferromagnet/antiferromagnet interface. This is attributed to the relatively large volume of our nanoparticles.