Phase behaviour of a continuous shouldered well model fluid. A grand canonical Monte Carlo study

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• 作者：Miha Luk&scaron ; ič^a ; ^{miha.luksic@fkkt.uni-lj.si} ; Barbara Hribar-Lee^a ; Orest Pizio^b
• 关键词：Liquids ; Soft-core model fluid ; Grand canonical Monte Carlo simulations ; Phase diagram
• 刊名：Journal of Molecular Liquids
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：228
• 期：Complete
• 页码：4-10
• 全文大小：1021 K
• 卷排序：228

文摘

Phase behaviour of CSW model fluid is studied by means of a GCMC simulations. Model has supercritical phase, and vapour-liquid & liquid-liquid phase coexistences. TMD is located in-between the liquid-vapour and liquid-liquid coexisting envelopes. Widom lines were constructed in the chemical potential-temperature phase diagram.