A 2D nickel-based energetic MOFs incorporating 3,5-diamino-1,2,4-triazole and malonic acid: Synthesis, crystal structure and thermochemical study
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- 作者：Qi Yang ; yangqi@nwu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Xiaxia Song ; Jing Ge ; Guowei Zhao ; Wendou Zhang ; Gang Xie ; Sanping Chen ; sanpingchen@126.com" class="auth_mail" title="E-mail the corresponding author ; Shengli Gao
- 关键词：3 ; 5-Diamino-1 ; 2 ; 4-triazole ; Malonic acid ; Energetic MOFs ; Standard molar enthalpy of formation ; Specific heat capacity
- 刊名：Journal of Chemical Thermodynamics
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：92
- 期：Complete
- 页码：132-138
- 全文大小：1797 K
文摘
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An energetic MOFs with dinuclear nickel unit has been synthesized and characterized.
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The Arrhenius equation, derived from kinetics analysis, is ln k = 55.89 − 332.01 × 103/RT.
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The standard molar enthalpy of formation of the compound is determined by a thermochemical cycle.
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The molar heat capacity at T = 298.15 K is determined to be 1.42 ± 0.11 J · K−1 · g−1.