One- and two-dimensional polymerisation of homoleptic M(II)-complexes of 4鈥?(3-pyridyl)-2,2鈥?6鈥?2鈥?terpyridine in the solid state: A combined study by XRD, cyclic voltammetry, NMR and UV-Vis spectroscopies
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- 作者：Amlan K. Pal ; Baptiste Laramé ; e-Milette ; Garry S. Hanan ; garry.hanan@umontreal.ca" class="auth_mail
- 关键词：Homoletic complexes ; Metalloligand ; Paramagnetic behaviour ; Terpyridine embrace ; MLCT versus d&ndash ; d transition
- 刊名：Inorganica Chimica Acta
- 出版年：1 July 2014
- 年：2014
- 卷：418
- 期：Complete
- 页码：15-22
- 全文大小：1713 K
文摘
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A series of 1st and 2nd row transition metal homoletic complexes of 3-PyTpy have been synthesized.
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Electrochemical and photophysical properties of these complexes are affected by the pendant 3-pyridyl group.
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A 2D-terpyridine embrace is formed for Co(II) and Cu(II)-complexes as PF6 salts.
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The terpyridine embrace is converted to 1D-ribbon in Fe(II)-complex as its BPh4 salt.