Borate-based ligands with soft heterocycles and their ruthenium complexes
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- 作者：Dipak Kumar Roy ; Rosmita Borthakur ; Soumalya Bhattacharyya ; V. Ramkumar ; Sundargopal Ghosh ; sghosh@iitm.ac.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Borate ; Scorpionate ; Linkage isomerism ; Ruthenium ; Cyclic voltammetry
- 刊名：Journal of Organometallic Chemistry
- 出版年：2015
- 出版时间：15 December 2015
- 年：2015
- 卷：799-800
- 期：Complete
- 页码：132-137
- 全文大小：694 K
文摘
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Various ruthenium hydrotrisborate complexes have been synthesized.
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Ligand connects to the metal and the boron centre through a common sulfur atom.
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Upon heating, compounds 3a,b change into their corresponding S→N linkage isomers.