Aluminium complexes of B- and N-based hydrides: Synthesis, structures and hydrogen storage properties
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- 作者：I. Dovgaliuk ; Y. Filinchuk ; yaroslav.filinchuk@uclouvain.be" class="auth_mail" title="E-mail the corresponding author
- 关键词：Aluminium ; Complex hydrides ; Crystal structure ; New materials ; Hydrogen storage
- 刊名：International Journal of Hydrogen Energy
- 出版年：2016
- 出版时间：14 September 2016
- 年：2016
- 卷：41
- 期：34
- 页码：15489-15504
- 全文大小：1770 K
文摘
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Al complexes with B- and N-based hydrides show good capacity for hydrogen storage.
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Al3+ is a Lewis acid, coordinating the initial light hydrides and the dehydrogenation products, favouring the reversibility.
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The factors influencing the stability and hydrogen purity are determined.