An efficient synthesis of iminoisoindolione derivatives by cobalt-catalyzed oxidative isocyanide insertion

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• 作者：Feihua Zou ; Xuwen Chen ; Wenyan Hao ; ^{wenyanhao@jxnu.edu.cn}
• 关键词：Oxidative isocyanide insertion ; Cobalt-catalyzed ; Iminoisoindoliones ; Heterocycles ; CH activation
• 刊名：Tetrahedron
• 出版年：2017
• 出版时间：9 February 2017
• 年：2017
• 卷：73
• 期：6
• 页码：758-763
• 全文大小：506 K
• 卷排序：73

文摘

A cobalt-catalyzed oxidative isocyanide insertion involving CH bond activation is reported. The reaction generates a variety of iminoisoindoliones in good yields. Isocyanide as a C1 source inserted into two nucleaphlies can construct heterocycle.