Supramolecular assembly of molecular gold(I) compounds: An evaluation of the competition and complementarity between aurophilic (Au鈰疉u) and conventional hydrogen bonding interactions
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- 作者：Edward R.T. Tiekink ; edward.tiekink@gmail.com" class="auth_mail ; edward.tiekink@um.edu.my" class="auth_mail
- 关键词：Gold compounds ; Aurophilic interactions ; Hydrogen bonding ; Crystal engineering
- 刊名：Coordination Chemistry Reviews
- 出版年：1 September 2014
- 年：2014
- 卷：275
- 期：Complete
- 页码：130-153
- 全文大小：6588 K
文摘
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Gold(I) compounds may associate via hydrogen bonding or aurophilic interactions.
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The propensity of hydrogen bond formation is far greater than Au鈰疉u interactions.
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Steric effects are important in militating Au鈰疉u interactions.
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Functional groups complexed to gold are more likely to form cyclic supramolecular synthons.