Synthesis, characterization, crystal structure of magnesium compound based 3, 3′, 5, 5′-azobenzentetracarboxylic acid and application as high-performance heterogeneous catalyst for cyanosilylation

详细信息    查看全文

• 作者：Yong-Peng Li ; Ling-Juan Zhang ; Wen-Juan Ji ; ^{ji18629288564@163.com}
• 关键词：Metal-organic framework ; Magnesium ; Azo-group ; Cyanosilylation ; Heterogeneous catalyst
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 April 2017
• 年：2017
• 卷：1133
• 期：Complete
• 页码：607-614
• 全文大小：3413 K
• 卷排序：1133

文摘

A highly stable porous Mg-abtc MOF has been synthesized by solvethermal method. Compound 1, with azo-group acting as Lewis base, has highly catalysis activity. The catalyst can be reused up to five time without obvious loss of activity.