Some unsymmetrical nickel 1,2-dithiolene complexes as candidate materials for optics and electronics

详细信息    查看全文

• 作者：George C. Anyfantis ; George C. Papavassiliou ; Nikos Assimomytis ; Aris Terzis ; Vassilis Psycharis ; Catherine P. Raptopoulou ; Panayotis Kyritsis ; Vladimiros Thoma ; Ioannis B. Koutselas
• 关键词：Metal 1 ; 2-dithiolenes ; Crystal structure ; Optical properties ; Electrochemical properties ; Devices
• 刊名：Solid State Sciences
• 出版年：2008
• 出版时间：December 2008
• 年：2008
• 卷：10
• 期：12
• 页码：1729-1733
• 全文大小：369 K

文摘

The unsymmetrical complexes Ni(tmedt)(dddt), Ni(dpedt)(dddt), Ni(tmedt)(dmit), and Ni(dpedt)(dmio) (where tmedt is trimethylene-ethylenedithiolate, dddt is 5,6-dihydro-1,4-dithin-2,3-dithiolate, dmit is 1,3-dithiol-2-thione-4,5-dithiolate, dpedt is diphenyl-ethylenedithiolate, and dmio is 1,3-dithiol-2-one-4,5-dithiolate) were prepared and their structural and physical properties investigated. The results were compared with those obtained from similar unsymmetrical and the corresponding symmetrical complexes. The new complexes were found to be stable in air and exhibit the necessary structural and physical properties in order to be candidate materials for optical and electronic devices.