Synthesis of chain-end multi-functionalized polyisoprene with a definite number of amino groups via living anionic copolymerization
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- 作者：Wu Bin Ying ; Ji Uk Jang ; Min Woo Lee ; Hee Sang Yang ; Da Som Moon ; Kyung Jin Lee ; kjlee@cnu.ac.kr" class="auth_mail" title="E-mail the corresponding author ; Bumjae Lee ; bjlee@cnu.ac.kr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Living anionic copolymerization ; Amino substituted 1 ; 1-diphenylethylene derivatives ; Chain-end multi-functionalized polymer ; Copolymerization composition equation ; A definite number of functional groups
- 刊名：Polymer
- 出版年：2016
- 出版时间：28 September 2016
- 年：2016
- 卷：101
- 期：Complete
- 页码：158-167
- 全文大小：1646 K
文摘
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Chain-end amine multi-functionalized polydienes could be synthesized via living anionic polymerization.
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The amine functionality could be well controlled by using our synthetic and calculation methodology.
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Polar additives do not affect the reactivity of DPE-NMe2 in the copolymerization with styrene.