Half-sandwich ruthenium(II) complexes with water-soluble Schiff base ligands: Synthesis and catalytic activity in transfer hydrogenation of carbonyl compounds

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• 作者：Somayeh Azizi Talouki^a ; Gholamhossein Grivani^a ; ^{grivani@du.ac.ir} ; Pascale Crochet^b ; ^{crochetpascale@uniovi.es} ; Victorio Cadierno^b
• 关键词：Schiff-base ligands ; Ionic ligands ; Ruthenium ; Transfer hydrogenation ; Ketones ; Aqueous catalysis
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 February 2017
• 年：2017
• 卷：456
• 期：Complete
• 页码：142-148
• 全文大小：755 K
• 卷排序：456

文摘

Four new ionic Schiff-base ligands have been synthesized. Their selective coordination as N,N-chelates to an arene-ruthenium(II) fragment affords highly water-soluble complexes. The derivatives prepared have proved to be active in the transfer hydrogenation of ketones and aldehydes in aqueous media.