Understanding the extraction and complexation of thorium using structurally modified CMPO functionalized pillar[5]arenes in ionic liquid: Experimental and theoretical investigations

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• 作者：Arijit Sengupta^a ; ^{arijita@barc.gov.in} ; Manpreet Singh^b ; Mahesh Sundarajan^c ; Lihua Yuan^d ; Yuyu Fang^d ; Xiangyang Yuan^d ; Wen Feng^d ; ^{wfeng9510@scu.edu.cn}
• 关键词：CMPO ; Thorium ; Pillar[5]arenes ; Extraction ; Mechanism
• 刊名：Inorganic Chemistry Communications
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：75
• 期：Complete
• 页码：33-36
• 全文大小：554 K
• 卷排序：75

文摘

CMPO-functionalized pillar[5]arenes: highly efficient and selective for Th4 + The extracted complex: [Th.L (NO3)]3 + species Oxalic acid quantitative stripping DFT: optimized ligand structure and metal-ligand complex Radio-resistant ligand