Influence of reaction mechanism accuracy on the chemical reactivity prediction of complex charring material in fire condition
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- 作者：Damien M. Marquisa ; damien.marquis@lne.fr" class="auth_mail" title="E-mail the corresponding author ; Benjamin Batiotb ; Eric Guillaumea ; c ; Thomas Rogaumeb
- 关键词：modelling ; reaction pathway ; charring material ; polyisocyanurate foam ; fire ; pyrolysis ; thermal decomposition
- 刊名：Journal of Analytical and Applied Pyrolysis
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：118
- 期：Complete
- 页码：231-248
- 全文大小：1969 K
文摘
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Application of modelistic method to determine reaction kinetics in pyrolysis modelling for fire safety applications.
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Example of application toPIR foam used widely.
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Definition of ordinarydifferential equations for thermolysis and thermo-oxidative decomposition.
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Definition of optimalreaction scheme using statistical criteria.
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Recommandations on suitable reaction sheme for application in fire modelling.