Synthesis, crystal structures and catalytic activity of Cu(II) and Mn(III) Schiff base complexes: Influence of additives on the oxidation catalysis of cyclohexane and 1-phenylehanol

详细信息    查看全文

• 作者：Oksana V. Nesterova^a ; Dmytro S. Nesterov^a ; ^{dmytro.nesterov@tecnico.ulisboa.pt} ; Agnieszka Krogul-Sobczak^b ; M. Fá ; tima C. Guedes da Silva^a ; ^{fatima.guedes@tecnico.ulisboa.pt} ; Armando J.L. Pombeiro^a ; ^{pombeiro@tecnico.ulisboa.pt}
• 关键词：Alkane oxidation ; Alcohol oxidation ; Hydrogen peroxide ; Alkyl radical ; Metal complex catalysis
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：506-515
• 全文大小：2008 K
• 卷排序：426

文摘

Oxidation of cyclohexane with H2O2 catalysed by copper and manganese complexes. Pronounced promoting effect of pyridine. Direct GCMS observation of cyclohexyl hydroperoxide as a main reaction product. The formation of chlorocyclohexane in the presence of HCl promoter. Solvent-free oxidation of phenylethanol with t-BuOOH.