Synthesis and crystallographic characterisation of Mg(H2dhtp)(H2O)5·H2O
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- 作者：Susan E. Henkelis ; seh24@st-andrews.ac.uk" class="auth_mail" title="E-mail the corresponding author ; Laura J. McCormick ljm22@st-andrews.ac.uk" class="auth_mail" title="E-mail the corresponding author ; David B. Cordes dbc21@st-andrews.ac.uk" class="auth_mail" title="E-mail the corresponding author ; Alexandra M.Z. Slawin amzs@st-andrews.ac.uk" class="auth_mail" title="E-mail the corresponding author ; Russell E. Morris rem1@st-andrews.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：MOF ; CPO-27 ; Mononuclear ; Hydrogen bonding ; Reflux
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：65
- 期：Complete
- 页码：21-23
- 全文大小：593 K
文摘
The first example of a non-polymeric Mg-H2dhtp complex is reported.
Obtained by one-pot reflux at lower pH than leads to a known MOF, CPO-27-Mg
Hydrogen bonding interactions construct a complex 3D network.