Pt-Au-Ag porous NPs were fabricated by selective removal of Ag from Pt-Au-Ag alloy. The porous NPs were formed with a particle size of 10 nm and a ligament size of 2 nm. The porous NPs are ultrastable and keep monodisperse in organic solvent for 100 days. Neither aggregations nor changes in light absorbance occurred to the porous NPs.